P. Shwethambika; J. Ishwara Bhat
Abstract
Theobroma cocoa dry bean extract (CDBE) was prepared by Soxhlet extraction method and was characterized for its chemical constituents using Fourier Transform-Infrared Spectroscopy (FT-IR), Gas chromatography-Mass spectroscopy (GC-MS) and also by Thermogravimetric Analysis-Differential Scanning Calorimetry ...
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Theobroma cocoa dry bean extract (CDBE) was prepared by Soxhlet extraction method and was characterized for its chemical constituents using Fourier Transform-Infrared Spectroscopy (FT-IR), Gas chromatography-Mass spectroscopy (GC-MS) and also by Thermogravimetric Analysis-Differential Scanning Calorimetry (TGA-DSC) techniques. FT-IR analysis gave information about the mostly like to be present functional groups in the extract. GC-MS analysis of the extract revealed the presence of important 07 chemical constituents with cis-13-octadecanoic acid as the major component. TGA-DSC study gave the idea about different stages of thermal decomposition of the chemical constituents present in the extract. CDBE was then tested for its ability to inhibit the corrosion rate of mild steel in 1.0M HCl solution medium by means of weight loss, Potentiodynamic polarization, and Electrochemical impedance spectroscopy (EIS) techniques. The weight loss experiments revealed the anticorrosive property of it on mild steel, which was found to increase with increase in the concentration of the inhibitor CDBE and decrease with an increase in temperature of corrosive medium. EIS results showed the adsorption of organic constituents present in the extract at the metal-solution interface. Potentiodynamic polarization studies revealed that CDBE functioned as a mixed type inhibitor. The surface morphological studies of mild steel surface were carried out by Scanning electron microscopy (SEM). The inhibition efficiency values obtained by electrochemical measurements were consistent with those from weight loss measurements and hence it can be proposed that CDBE as a potent inhibitor towards corrosion of mild steel under acidic conditions.
N. Raghavendra
Abstract
In this investigation, the application of the Ceftin drug on the prevention of the corrosion of carbon steel in 3 % NaCl solution was examined through weight loss (mass loss), gasometric and atomic absorption spectroscopy techniques. The effectiveness of the Ceftin drug as corrosion inhibitor for carbon ...
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In this investigation, the application of the Ceftin drug on the prevention of the corrosion of carbon steel in 3 % NaCl solution was examined through weight loss (mass loss), gasometric and atomic absorption spectroscopy techniques. The effectiveness of the Ceftin drug as corrosion inhibitor for carbon steel was proved by weight loss, gasometric and atomic absorption spectroscopy results. The increase in the Ceftin drug concentration decreases the carbon steel weight loss in the 3 % NaCl solution, which is due to the formation of invisible thick layer on the carbon steel in the 3 % NaCl solution. The increase in the contact time decreases the corrosion inhibition property of expired Ceftin drug. Gasometric studies show that, the amount of hydrogen gas evolved decreases with rise in the concentration of 3 % NaCl solution. The results of atomic absorption spectroscopy well support the weight loss (mass loss) and gasometric results.
