Adsorption of CO2 on Zeolite 13X Prepared from Modified Natural Iranian Kaolin

Authors

1 Faculty of Oil, Gas and Chemical Engineering, Semnan University, Semnan, Iran

2 Research Laboratory of Nanoporous Materials, Faculty of Chemistry, Iran University of Science and Technology, FarjamStreet, Narmak, Tehran 16846-13114, Iran

Abstract

Synthesis of zeolite 13X from modified natural Iranian kaolin at 65˚C for 72 h at various concentration of NaOH solution was investigated. Metakaolinization process was done at 900˚C for 2 h. NaOH solution with different concentrations, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5 and 4 M were separately mixed with metakaolins. A mixture of zeolite 13X, A, quartz and hydroxysodalite (HS) was obtained. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The prepared zeolite 13X has been used to study the adsorption of carbon dioxide, and the results are compared with commercial zeolite 13X.

Keywords

References

  1. Zhao, Z., Cui, X., Ma, J., Li, R., 2007.Adsorption of carbon dioxide on alkali-modified zeolite 13X adsorbents. International Journal of Greenhouse Gas Control. 1: 355-359.
  2. Lee, J.S.,Kim, J.H.,Kim, J.T.,Suh, J.K.,Lee, J.M., 2002. Adsorption equilibria of CO2 on zeolite 13X and zeolite X/activated carbon composite,Journal of Chemical Engineering Data. 47: 1237-1242.
  3. Rege, S.U., Yang, R.T.,Buzanowski, A.M., 2000.Sorbents for air prepurification in air separation Chemical Engineering Science . 55: 4827-4832.
  4. Millward, A.R.,Yaghi, O.M., 2005. Metal-Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature, Journal of American Chemical Society 127: 7998-17999.
  5. Chen,C., Kim, J.,Yang, D.A, Ahn,W.S., 2011.Carbon dioxide adsorption over zeolite-like metal organic frameworks (ZMOFs) having a sod topology: Structure and ion-exchange effect, Chemical Engineering. 168: 1134-1139.
  6. Chen,C.,Ahn,W.S., 2011.CO2 capture using mesoporous alumina prepared by a sol-gel process, Chemical Engineering. 166: 646-652.
  7. Chen, C.,Kim, J. Ahn, W.S., 2012.Efficient carbon dioxide capture over a nitrogen-rich carbon having a hierarchical micro-mesopore structure, Fuel. 95: 360-364.
  8. Hao,G.P.,Li, W.C.,Qian, D.,Lu, A.H., 2010. Rapid Synthesis of Nitrogen-Doped Porous Carbon Monolith for CO2 Capture, Advanced Materials. 22: 853-857.
  9. Chen, C.,Park, D.W.,Ahn,W.S., 2014.CO2 capture using zeolite 13X prepared from bentonite, Applied Surface Science 292: 63-68.
  10. Alshameri, A.,Yan, C.J.,Yasir, A.A.,Ammar, S.D., Abdullateef, I.,Zhao,C.Y.,Wang, H.Q., 2014. An investigation into the adsorption removal of ammonium by salt activated Chinese (Hulaodu) natural zeolite: Kinetics, isotherms, and thermodynamics, Journal of Taiwan Institute of Chemical Engineers 45: 554-564.
  11. Tosheva,L.,Vltchev,V.P., 2005. Nanozeolites: Synthesis,

    Crystallization Mechanism, and Applications,  Chemical Materials. 17: 2494-2513.
  12. Cundy, C.S.,Cox, P.A., 2003.The Hydrothermal Synthesis of Zeolites: History and Development from the Earliest Days to the Present Time, Chemical Reviews. 103: 663-701.
  13. Yan,Y., Bein, T.,1995. Zeolite Thin Films with Tunable Molecular Sieve Function ,Journal of Americal Chemical Society, 117: 9990-9994.
  14. Kazemian,H.,Modarress,H.,Kazemi,M.,Farhadi,F.,2009. Synthesis of submicron zeolite LTA particles from natural clinoptilolite and industrial grade chemicals using one stage procedure, Powder Technology. 196: 22-27.
  15. Ma,Y.,Yan,C.,Alshameri, A., Qiu, X.,Zhao, C.,Ii, D., 2014. Synthesis and characterization of 13X zeolite from low-grade natural kaolin, Advanced Powder. Technology. 25: 495-500.
  16. Chen, D.,Hu, X., Shi, L.,Cui, Q.,Wang, H.Y.,Yao, H.Q.,2012. Synthesis and characterization of zeolite X from lithium slag ,Applied Clay Science. 59: 148-151.
  17. Kazemian, H.,Naghdali, Z.,Kashani, T.G., Farhadi,  F.,2010. Conversion of high silicon fly ash to Na-P1 zeolite: alkaline fusion followed by hydrothermal crystallization, Advanced. Powder Technology. 21: 279-284.
  18. Wajima, T.,Haga, M.,Kuzawa, K.,Ishimoto,H., Tamada, O.,Ito, K.,Nishiyama,T., Downs, R.T.,Pakovan, J.F., 2006.Zeolite synthesis from paper sludge ash at low temperature (90 ◦C) with addition of diatomite,Journal of Hazardous Materials. 132: 244-252.
  19. Pornomo,C.W.,Salim,C.,Hinode,H.,2012. Synthesis of pure Na–X and Na–A zeolite from bagasse fly ash , Microporous and Mesoporous Materials. 162: 6-13.
  20. Machado,N.R.C.F.,Miotto,D.M.M., 2005.Synthesis of Na–A and –X zeolites from oil shale ash, Fuel. 84: 2289-2294.
  21. Tanaka,H., Fujii, A.,2009. Effect of stirring on the dissolution of coal fly ash and synthesis of pure-form Na-A and -X zeolites by two-step process, Advanced Powder Technology. 20: 473-479.
  22. Colina,F.G.,Liorens, J.,2007. Study of the dissolution of dealuminated kaolin in synthesis, Microporous and Mesoporous Materials, 100: 302-306.
  23. Colina,F.G.,Esplugas,S., Costa, J., 2002.High-Temperature Reaction of Kaolin with Sulfuric Acid , Industrial & Engineering Chemistry Research. 41: 4168-4173.
  24. Gougazeh,M., Buhl, J.C.,2013. Synthesi and characterization of zeolite A by hydrothermal transformation of natural jordonian kaolin, JAAUBAS 15: 35-41.
  25. Cavenati, S.,Grande, C.A.,Rodrigues, A.E., 2004.Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressure, Journal of Chemical Engineering 49: 1095-1099.
  26. Xu, X., Song, C., Andresen, J.M, Miller, B.G.,Scaroni, A.W., 2003.preparation and characterization of novel CO2 molecular basket adsorbents based on polymer-modified mesoporous molecular sieve MCM-41, Microporous and Mesoporous Materials. 62: 29-34.
  27. Lu, C.M.,Liu, J.,Xiao, K.,Harris, A.T., 2010. Microwave enhanced synthesis of MOF-5 and its CO2 capture ability at moderate temperatures across multiple capture and release cycles, Chemeical Engineering Journal. 156: 465-470.
Iranian (Iranica) Journal of Energy & Environment
Volume 7, Issue 3
Summer 2016
Pages 304-307

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