S. A. Abdulkareem; J. O. Ighalo; A. G. Adeniyi
Abstract
The prospective reuse of iron fillings from the milling machine and polystyrene in the solid waste streams in the production of plastic composites were considered in this study. The preparation, electrical properties, density, void fraction and particle distributions of the solvated polystyrene filled ...
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The prospective reuse of iron fillings from the milling machine and polystyrene in the solid waste streams in the production of plastic composites were considered in this study. The preparation, electrical properties, density, void fraction and particle distributions of the solvated polystyrene filled composites were all investigated as a function of recycled iron fillings concentration. The composites were developed by hand layup technique and cured by casting under ambient conditions (25 ± 2oC) for 7 days. The compared micrographs confirmed well-dispersed recycled iron fillings in polystyrene matrix and decreasing void fraction as iron filling increases in the composites. The highest electrical conductivity and density values of the composites were obtained at the highest iron filling composition of 40 wt% as 5.91 × 10-07 S/cm and 1.31 g/cm3, respectively. The developed iron polystyrene composite has good electrical properties, making it suitable to be an alternative material for metals.
J. O. Ighalo; A. A. Adelodun; A. G. Adeniyi; C. A. Igwegbe
Abstract
Statistical modelling was employed to analyze the effect of sorbate-sorbent interphase on the adsorption of pesticides and herbicides from aqueous media. The dataset used for this study was sourced from relevant and reputable published papers in the past five years. Sixty-six lines of data were analyzed ...
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Statistical modelling was employed to analyze the effect of sorbate-sorbent interphase on the adsorption of pesticides and herbicides from aqueous media. The dataset used for this study was sourced from relevant and reputable published papers in the past five years. Sixty-six lines of data were analyzed using response surface methodology (RSM) and historical data design (HDD) on Design expert. Five parameters were considered in the study: adsorbate’s relative molecular mass (RMM), adsorbent specific surface area (SBET), adsorbent effective surface area eSBET (i.e., the portion of the SBET occupied by the sorbate molecules), the water solubility of adsorbate, and adsorbate preferential adsorption (i.e., the ratio of the amount of sorbate on the sorbent to the amount in solution). From the analysis of variance, it was observed that the SBET of the adsorbent was the most significant determining for the adsorption capacity, q (at a significance level of p <0.05). Other significant factors were the RMM, eSBET, and the preferential adsorption. Generally, solubility did not show any significant influence on the q. The response surface model had an R2 value of 0.9945 and an adjusted R2 value of 0.9927. Conclusively, the q of an adsorbent towards an herbicide or a pesticide increases with increasing eSBET and SBET, irrespective of the sorbate’s solubility and molecular mass.
A. G. Adeniyi; J. O. Ighalo
Abstract
In this preliminary investigation, the production of liquid fertilizer from rock phosphate and dolomite in Nigeria using the nitrophosphate is evaluated. Rock phosphate was obtained from Sokoto state, Nigeria. Dolomite was obtained from Edo state, Nigeria. This work contains a detailed description of ...
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In this preliminary investigation, the production of liquid fertilizer from rock phosphate and dolomite in Nigeria using the nitrophosphate is evaluated. Rock phosphate was obtained from Sokoto state, Nigeria. Dolomite was obtained from Edo state, Nigeria. This work contains a detailed description of the procedure and the associated chemical reactions. There are also important explanations of some physical observations and their possible implications in a large scale process. The time frame for each batch should not exceed 1 h considering the reaction rates and the temperatures are likely not to exceed 80oC at any point in the process. It was observed that the potassium, phosphorus and nitrogen content of both fertilizers are similar but the calcium content of the product from dolomite was higher than the other products. Furthermore, possible process design modifications based on these physical observations are proposed in line with product quality, safety, cost and other considerations. The process was ultimately successful and recommendations were made based on several aspects of the process.
A. G. Adeniyi; D. V. Onifade; J. O. Ighalo; S. A. Abdulkareem; M. K. Amosa
Abstract
Plantain stalks obtained from solid waste stream of Ganmo market in Ilorin was used in this study. Natural fibres extraction from waste plantain stalk was achieved using biological retting methods. The natural fibre was rented from the waste stalk after 24 days of soaking in water. The extracted fibres ...
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Plantain stalks obtained from solid waste stream of Ganmo market in Ilorin was used in this study. Natural fibres extraction from waste plantain stalk was achieved using biological retting methods. The natural fibre was rented from the waste stalk after 24 days of soaking in water. The extracted fibres were exposed to 2, 4 and 6% alkali solution (NaOH) treatment for two hours, washed and dried in the oven for 7 hours. Elemental analysis of raw plantain fibres showed the presence of elements like Indium, Potassium, Silicon and Calcium among others. Tensile strength analysis of the fibres, for single fibre strands showed that the 2% treated fibre showed distinctly promising potential with the highest tensile characteristics of young modulus, stress at break and force at peak of 52864.366N/mm2, 5398.536N/mm2 and 2.650N, respectively. Evaluation of the chemical composition of plantain by FTIR spectroscopy indicated that treatment of natural fibres using NaOH beyond 2% have a negative impact on the plantain fibre properties. Through alkali exposure, the fibre configuration presents small variations in composition. It is consequently apparent that alkali treatment with concentration of less than 2% NaOH is sufficient to remove hemicelluloses and to obtain the optimum tensile effect.